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1

Borazine-CF3- Adducts for Rapid, Room Temperature, and Broad Scope Trifluoromethylation

Geri, Jacob Benjamin, Wade Wolfe, Michael McCreery, Szymczak, Nathaniel Kolnik

Journal:

Angewandte Chemie International Edition

Year:

2017

Language:

english

File:

PDF, 2.22 MB

english, 2017

2

Hydrogen Transfer Catalysis Beyond the Primary Coordination Sphere

Hale, Lillian V. A., Szymczak, Nathaniel K.

Journal:

Year:

2018

Language:

english

File:

PDF, 4.25 MB

english, 2018

3

In Situ Multinuclear NMR Spectroscopic Studies of the Thermal Decomposition of Ammonia Borane in Solution

Wendy J. Shaw, John C. Linehan, Nathaniel K. Szymczak, David J. Heldebrant, Clem Yonker, Donald M. Camaioni, R. Tom Baker, Tom Autrey

Journal:

Angewandte Chemie

Year:

2008

Language:

english

File:

PDF, 383 KB

english, 2008

4

In Situ Multinuclear NMR Spectroscopic Studies of the Thermal Decomposition of Ammonia Borane in Solution

Wendy J. Shaw, John C. Linehan, Nathaniel K. Szymczak, David J. Heldebrant, Clem Yonker, Donald M. Camaioni, R. Tom Baker, Tom Autrey

Journal:

Angewandte Chemie International Edition

Year:

2008

Language:

english

File:

PDF, 383 KB

english, 2008

5

Aspects of dihydrogen coordination chemistry relevant to reactivity in aqueous solution

Nathaniel K. Szymczak, David R. Tyler

Journal:

Coordination Chemistry Reviews

Year:

2008

Language:

english

File:

PDF, 1.42 MB

english, 2008

6

Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl 2 ] 2 ? In Operando XAFS, Kinetic, and Crucial Kinetic Poisoning Evidence for Subnanometer Rh 4 Cluster-Based Benzene Hydrogenation Catalysis

Bayram, Ercan, Linehan, John C., Fulton, John L., Roberts, John A. S., Szymczak, Nathaniel K., Smurthwaite, Tricia D., Özkar, Saim, Balasubramanian, Mahalingam, Finke, Richard G.

Journal:

Journal of the American Chemical Society

Year:

2011

Language:

english

File:

PDF, 2.59 MB

english, 2011

7

Reduction of Borazines Mediated by Low-Valent Chromium Species

Carter, Tyler J., Kampf, Jeff W., Szymczak, Nathaniel K.

Journal:

Angewandte Chemie

Year:

2012

Language:

english

File:

PDF, 804 KB

english, 2012

8

Reduction of Borazines Mediated by Low-Valent Chromium Species

Carter, Tyler J., Kampf, Jeff W., Szymczak, Nathaniel K.

Journal:

Angewandte Chemie International Edition

Year:

2012

Language:

english

File:

PDF, 799 KB

english, 2012

9

A Transition Metal Lewis Acid/Base Triad System for Cooperative Substrate Binding

Tutusaus, Oscar, Ni, Chengbao, Szymczak, Nathaniel K.

Journal:

Journal of the American Chemical Society

Year:

2013

Language:

english

File:

PDF, 621 KB

english, 2013

10

Base-Free, Acceptorless, and Chemoselective Alcohol Dehydrogenation Catalyzed by an Amide-Derived NNN -Ruthenium(II) Hydride Complex

Tseng, Kuei-Nin T., Kampf, Jeff W., Szymczak, Nathaniel K.

Journal:

Organometallics

Year:

2013

Language:

english

File:

PDF, 554 KB

english, 2013

11

Coordination Chemistry of H 2 and N 2 in Aqueous Solution. Reactivity and Mechanistic Studies Using trans -Fe II (P 2 ) 2 X 2 -Type Complexes (P 2 = a Chelating, Water-Solubilizing Phosphine)

Gilbertson, John D., Szymczak, Nathaniel K., Crossland, Justin L., Miller, Warren K., Lyon, David K., Foxman, Bruce M., Davis, Joclyn, Tyler, David R.

Journal:

Inorganic Chemistry

Year:

2007

Language:

english

File:

PDF, 216 KB

english, 2007

12

Oxidant-Free Conversion of Primary Amines to Nitriles

Tseng, Kuei-Nin T., Rizzi, Andrew M., Szymczak, Nathaniel K.

Journal:

Journal of the American Chemical Society

Year:

2013

Language:

english

File:

PDF, 364 KB

english, 2013

13

A 3-Fold-Symmetric Ligand Based on 2-Hydroxypyridine: Regulation of Ligand Binding by Hydrogen Bonding

Moore, Cameron M., Quist, David A., Kampf, Jeff W., Szymczak, Nathaniel K.

Journal:

Inorganic Chemistry

Year:

2014

Language:

english

File:

PDF, 229 KB

english, 2014

14

Manganese-Mediated Hydride Delivery to a Borazine by Stepwise Reduction and Protonation

Carter, Tyler J., Wang, Justin Y., Szymczak, Nathaniel K.

Journal:

Organometallics

Year:

2014

Language:

english

File:

PDF, 442 KB

english, 2014

15

When is a Nanoparticle a Cluster? An Operando EXAFS Study of Amine Borane Dehydrocoupling by Rh 4-6 Clusters

Fulton, John L., Linehan, John C., Autrey, Tom, Balasubramanian, Mahalingam, Chen, Yongsheng, Szymczak, Nathaniel K.

Journal:

Journal of the American Chemical Society

Year:

2007

Language:

english

File:

PDF, 636 KB

english, 2007

16

H 2 Activation in Aqueous Solution: Formation of trans -[Fe(DMeOPrPE) 2 H(H 2 )] + via the Heterolysis of H 2 in Water

Gilbertson, John D., Szymczak, Nathaniel K., Tyler, David R.

Journal:

Inorganic Chemistry

Year:

2004

Language:

english

File:

PDF, 56 KB

english, 2004

17

Reduction of N 2 to Ammonia and Hydrazine Utilizing H 2 as the Reductant

Gilbertson, John D., Szymczak, Nathaniel K., Tyler, David R.

Journal:

Journal of the American Chemical Society

Year:

2005

Language:

english

File:

PDF, 52 KB

english, 2005

18

Theoretical Studies of N 2 Reduction to Ammonia in Fe(dmpe) 2 N 2

Yelle, Robert B., Crossland, Justin L., Szymczak, Nathaniel K., Tyler, David R.

Journal:

Inorganic Chemistry

Year:

2009

Language:

english

File:

PDF, 826 KB

english, 2009

19

Aqueous Coordination Chemistry of H 2 : Why is Coordinated H 2 Inert to Substitution by Water in trans -Ru(P 2 ) 2 (H 2 )H + -type Complexes (P 2 = a Chelating Phosphine)?

Szymczak, Nathaniel K., Braden, Dale A., Crossland, Justin L., Turov, Yevgeniya, Zakharov, Lev N., Tyler, David R.

Journal:

Inorganic Chemistry

Year:

2009

Language:

english

File:

PDF, 858 KB

english, 2009

20

Coordination of aminoborane, NH2BH2, dictates selectivity and extent of H2 release in metal-catalysed ammonia borane dehydrogenation

Pons, Vincent, Baker, R. Tom, Szymczak, Nathaniel K., Heldebrant, David J., Linehan, John C., Matus, Myrna H., Grant, Daniel J., Dixon, David A.

Journal:

Chemical Communications

Year:

2008

Language:

english

File:

PDF, 521 KB

english, 2008

21

Solution Chemistry of a Water-Soluble η 2 -H 2 Ruthenium Complex: Evidence for Coordinated H 2 Acting as a Hydrogen Bond Donor

Szymczak, Nathaniel K., Zakharov, Lev N., Tyler, David R.

Journal:

Journal of the American Chemical Society

Year:

2006

Language:

english

File:

PDF, 125 KB

english, 2006

22

A tris(2-quinolylmethyl)amine scaffold that promotes hydrogen bonding within the secondary coordination sphere

Moore, Cameron M., Szymczak, Nathaniel K.

Journal:

Dalton Transactions

Year:

2012

Language:

english

File:

PDF, 690 KB

english, 2012

23

Detection of hydrogen bonding in solution: A 2H nuclear magnetic resonance method based on rotational motion of a donor/acceptor complex

Szymczak, Nathaniel K., Oelkers, Alan B., Tyler, David R.

Journal:

Physical Chemistry Chemical Physics

Year:

2006

Language:

english

File:

PDF, 657 KB

english, 2006

24

Kinetic and thermodynamic investigation of hydrogen release from ethane 1,2-di-amineborane

Neiner, Doinita, Karkamkar, Abhi, Bowden, Mark, Joon Choi, Young, Luedtke, Avery, Holladay, Jamie, Fisher, Allison, Szymczak, Nathaniel, Autrey, Tom

Journal:

Energy & Environmental Science

Year:

2011

Language:

english

File:

PDF, 410 KB

english, 2011

25

Redox rich dicobalt macrocycles as templates for multi-electron transformations

Szymczak, Nathaniel K., Berben, Louise A., Peters, Jonas C.

Journal:

Chemical Communications

Year:

2009

Language:

english

File:

PDF, 1.05 MB

english, 2009

26

Arrested chloride abstraction from trans-RuCl2(DMeOPrPE)2 with TlPF6; formation of a 1-D coordination polymer having unusual octahedral coordination around thallium(i)

Szymczak, Nathaniel K., Han, Fusen, Tyler, David R.

Journal:

Dalton Transactions

Year:

2004

Language:

english

File:

PDF, 133 KB

english, 2004

27

Regulation of Iron-Catalyzed Olefin Hydroboration by Ligand Modifications at a Remote Site

Tseng, Kuei-Nin T., Kampf, Jeff W., Szymczak, Nathaniel K.

Journal:

Year:

2015

Language:

english

File:

PDF, 1.36 MB

english, 2015

28

Beyond H2: exploiting 2-hydroxypyridine as a design element from [Fe]-hydrogenase for energy-relevant catalysis

Moore, Cameron M, Dahl, Eric W, Szymczak, Nathaniel K

Journal:

Current Opinion in Chemical Biology

Year:

2015

Language:

english

File:

PDF, 1.37 MB

english, 2015

29

Nitrite reduction by copper through ligand-mediated proton and electron transfer

Moore, Cameron M., Szymczak, Nathaniel K.

Journal:

Chemical Science

Year:

2015

Language:

english

File:

PDF, 491 KB

english, 2015

30

Determination of the Dominant Catalyst Derived from the Classic [RhCpCl 2 ] 2 Precatalyst System: Is it Single-Metal Rh 1 Cp-Based, Subnanometer Rh 4 Cluster-Based, or Rh(0) n Nanoparticle-Based Cyclohexene Hydrogenation Catalysis at Room Temperature and Mild Pressures?

Bayram, Ercan, Linehan, John C., Fulton, John L., Szymczak, Nathaniel K., Finke, Richard G.

Journal:

Year:

2015

Language:

english

File:

PDF, 671 KB

english, 2015

31

Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ 2P , P ′}dichloridoosmium(II)

Szymczak, Nathaniel K., Zakharov, Lev N., Tyler, David R.

Journal:

Acta Crystallographica Section E Structure Reports Online

Year:

2011

Language:

english

File:

PDF, 537 KB

english, 2011

32

Dehydrogenative Oxidation of Primary Amines to Nitriles

Tseng, Kuei-Nin, Szymczak, Nathaniel

Journal:

Year:

2014

Language:

english

File:

PDF, 585 KB

english, 2014

33

Mechanism of N , N , N -Amide Ruthenium(II) Hydride Mediated Acceptorless Alcohol Dehydrogenation: Inner-Sphere β-H Elimination versus Outer-Sphere Bifunctional Metal–Ligand Cooperativity

Tseng, Kuei-Nin T., Kampf, Jeff W., Szymczak, Nathaniel K.

Journal:

Year:

2015

Language:

english

File:

PDF, 3.70 MB

english, 2015

34

Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding

Moore, Cameron M., Szymczak, Nathaniel K.

Journal:

Chemical Communications

Year:

2015

Language:

english

File:

PDF, 2.06 MB

english, 2015

35

A Proton-Switchable Bifunctional Ruthenium Complex That Catalyzes Nitrile Hydroboration

Geri, Jacob B., Szymczak, Nathaniel K.

Journal:

Journal of the American Chemical Society

Year:

2015

Language:

english

File:

PDF, 1.61 MB

english, 2015

36

Upgrading Ethanol to 1-Butanol with a Homogeneous Air-Stable Ruthenium Catalyst

Tseng, Kuei-Nin Timothy, Lin, Steve, Kampf, Jeffrey F., Szymczak, Nathaniel

Journal:

Chemical Communications

Year:

2016

Language:

english

File:

PDF, 653 KB

english, 2016

37

Simple Ligand Modifications with Pendent OH Groups Dramatically Impact the Activity and Selectivity of Ruthenium Catalysts for Transfer Hydrogenation: The Importance of Alkali Metals

Moore, Cameron M., Bark, Byongjoo, Szymczak, Nathaniel K.

Journal:

Year:

2016

Language:

english

File:

PDF, 2.12 MB

english, 2016

38

Evaluating Activity for Hydrogen-Evolving Cobalt and Nickel Complexes at Elevated Pressures of Hydrogen and Carbon Monoxide

McCrory, Charles C. L., Szymczak, Nathaniel K., Peters, Jonas C.

Journal:

Electrocatalysis

Year:

2016

Language:

english

File:

PDF, 1.89 MB

english, 2016

39

Discovery of low energy pathways to metal-mediated BN bond reduction guided by computation and experiment

Carter, Tyler J., Heiden, Zachariah M., Szymczak, Nathaniel K.

Journal:

Chemical Science

Year:

2015

Language:

english

File:

PDF, 861 KB

english, 2015

40

The Mechanism of Acceptorless Amine Double Dehydrogenation by N,N,N -Amide Ruthenium(II) Hydrides: A Combined Experimental and Computational Study

Hale, Lillian V. A., Malakar, Tanmay, Tseng, Kuei-Nin T., Zimmerman, Paul M., Paul, Ankan, Szymczak, Nathaniel K.

Journal:

Year:

2016

Language:

english

File:

PDF, 4.90 MB

english, 2016

41

Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex

Dahl, Eric W., Szymczak, Nathaniel K.

Journal:

Angewandte Chemie

Year:

2016

Language:

english

File:

PDF, 1.99 MB

english, 2016

42

ChemInform Abstract: 6,6′-Dihydroxy Terpyridine: A Proton-Responsive Bifunctional Ligand and Its Application in Catalytic Transfer Hydrogenation of Ketones.

Moore, Cameron M., Szymczak, Nathaniel K.

Journal:

Year:

2013

File:

PDF, 28 KB

2013

43

Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex

Dahl, Eric W., Szymczak, Nathaniel K.

Journal:

Angewandte Chemie International Edition

Year:

2016

Language:

english

File:

PDF, 2.03 MB

english, 2016

44

ChemInform Abstract: Oxidant-Free Conversion of Primary Amines to Nitriles.

Tseng, Kuei-Nin T., Rizzi, Andrew M., Szymczak, Nathaniel K.

Journal:

Year:

2014

File:

PDF, 28 KB

2014

45

ChemInform Abstract: A Proton-Switchable Bifunctional Ruthenium Complex that Catalyzes Nitrile Hydroboration.

Geri, Jacob B., Szymczak, Nathaniel K.

Journal:

Year:

2016

File:

PDF, 25 KB

2016

46

Modular Attachment of Appended Boron Lewis Acids to a Ruthenium Pincer Catalyst: Metal–Ligand Cooperativity Enables Selective Alkyne Hydrogenation

Tseng, Kuei-Nin T., Kampf, Jeff W., Szymczak, Nathaniel K.

Journal:

Journal of the American Chemical Society

Year:

2016

Language:

english

File:

PDF, 1.41 MB

english, 2016

47

Stereoretentive Deuteration of α-Chiral Amines with D 2 O

Hale, Lillian V. A., Szymczak, Nathaniel K.

Journal:

Journal of the American Chemical Society

Year:

2016

Language:

english

File:

PDF, 824 KB

english, 2016

48

Second sphere ligand modifications enable a recyclable catalyst for oxidant-free alcohol oxidation to carboxylates

Dahl, Eric W., Louis-Goff, Thomas, Szymczak, Nathaniel K.

Journal:

Chemical Communications

Year:

2017

Language:

english

File:

PDF, 1.64 MB

english, 2017

49

Testing the Push–Pull Hypothesis: Lewis Acid Augmented N 2 Activation at Iron

Geri, Jacob B., Shanahan, James P., Szymczak, Nathaniel K.

Journal:

Journal of the American Chemical Society

Year:

2017

Language:

english

File:

PDF, 1.06 MB

english, 2017

50

Recyclable Trifluoromethylation Reagents from Fluoroform

Geri, Jacob B., Szymczak, Nathaniel K.

Journal:

Journal of the American Chemical Society

Year:

2017

Language:

english

File:

PDF, 1.44 MB

english, 2017